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By Carey F., Sundberg R.

ISBN-10: 0306462443

ISBN-13: 9780306462443

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1972, 38, 97. Irgolic, K. J. in Houben-Weyl-Methods of Organic Chemistry. 4th edn, Vol. E12b, p. 389. Georg Thieme, Stuttgart, 1990. 34 3. PREPARATION OF THE PRINCIPAL CLASSES OF ORGANIC TELLURIUM 9. Hope, E. ; Levanson, W. Organometallics 1988, 7, 78. 10. ; Beck, A. K. Chem. Ber. 1975, 108, 314. 11. Lederer, K. Ber. Dtsch. Chem. Ges. ; Klar, G. Z. Anorg. AlIg. Chem. 1977, 435, 98. 12. Pierini, A. ; Rossi, R. A. J. Organomet. Chem. 1979, 168, 163. 13. Pierini, A. ; Rossi, R. A. J. Org. Chem. 1979, 44, 4667.

Engman, C. Synthesis 1980, 569. 26. Voronkov, M. ; Stankevich, V. ; Rodkniko, P. ; Korchevin, N. ; Deryagina, E. ; Trofimov, B. A. J. Gen. Chem. USSR 1987, 57, 2398. 27. ; Zhou, X. Synth. Commun. 1986, 16, 1849. 28. Einstein, F. ; Jones, C. H. ; Sharma, R. D. Can. J. Chem. 1983, 61, 2611. 29. Li, C. ; Harpp, D. N. Tetrahedron Lett. 1990, 31, 6291. 1 From sodium telluride and non-activated aryl halides The normal low reactivity of aryl halides towards nucleophilic reagents is not generally observed in their reaction with alkali tellurides.

9) Organyltellurium trichlorides and diorganyltellurium dichlorides are prepared starting from the electrophilic tellurium tetrachloride (or aryltellurium trichlorides) by: • • • • condensation reactions with active methylene compounds; addition to a CϭC bond (or a CϵC bond, not shown in the scheme); electrophilic substitution in aromatic hydrocarbons; and reaction with organomercury chlorides. Organyltellurium trichlorides and the not directly accessible tribromides and triiodides are obtained by the halogenolysis of the Te–Te bond of the corresponding ditellurides.

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Advanced Organic Chemistry. Reactions and Synthesis by Carey F., Sundberg R.


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